Synthesis, structure and biological activity of zinc(II) pincer complexes with 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119627
Abstract: Abstract The reaction of 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine (BPT) pincer ligand with Zn(NO3)2 and Zn(ClO4)2·6H2O/HCl yielded, [Zn(BPT)(NO3)2] (2), and [Zn(BPT)(H2O)Cl]ClO4 (3) complexes, respectively. However, zinc(II) chloride with BPT involved C N rupture and formed instead [Zn(DMP)2Cl2] (1) complex… read more here.
Keywords: pincer; methoxy triazine; dimethyl pyrazol; pyrazol methoxy ... See more keywords
Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol
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DOI: 10.1016/j.mencom.2019.01.013
Abstract: The new complex [Cu2(H2L)Cl3] with axial chloride ions coordination based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol was obtained and its crystal structure was determined. Magnetic studies revealed the presence of antiferromagnetic exchange interaction of −193 cm−1 that is extremely… read more here.
Keywords: based methyl; pyrimidin hydrazono; methyl bis; dimethyl pyrimidin ... See more keywords
Mixed azido/phenoxido bridged trinuclear Cu(ii) complexes of Mannich bases: Synthesis, structures, magnetic properties and catalytic oxidase activities.
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DOI: 10.1039/c8dt01400k
Abstract: Three similar Mannich base ligands viz. N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-dimethyl-1,3-diaminopropane (H2L1), N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-dimethyl-1,2-diaminoethane (H2L2) and N,N-bis(3,5-dimethyl-2-hydroxybenzyl)-N',N'-diethyl-1,2-diaminoethane (H2L3) upon reaction with Cu(CH3COO)2·H2O produced dinuclear complexes [Cu2L21-3]. The reaction of each of these isolated dimeric species with Cu(ClO4)2·6H2O and NaN3 resulted… read more here.
Keywords: dimethyl; dimethyl hydroxybenzyl; 2cu h2o; bis dimethyl ... See more keywords
Bis(catecholato-κ2 O,O′)bis(dimethyl sulfoxide-κO)titanium(IV)
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DOI: 10.1107/s2056989022002638
Abstract: Bis(catecholato)bis(DMSO)titanium crystallizes with two crystallographically independent molecules related by pseudo-glide symmetry in a distorted octahedral O6 donor-atom geometry around titanium. read more here.
Keywords: bis; bis dimethyl; dimethyl sulfoxide; catecholato bis ... See more keywords