THE REACTION OF 2,5-BIS[(DIMETHYLAMINO)METHYL]HYDROQUINONE AND 3-(DIMETHYLAMINO)-2-CYCLOHEXEN-1-ONES
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DOI: 10.1007/6126
Abstract: How to Cite Osyanin, V. A.; Ivleva, E. A.; Klimochkin, Yu. N. Chem. Heterocycl. Compd. 2010 , 46 , 1011. [ Khim. Geterotsikl. Soedin. 2010 , 1251.] For this article in the English edition see… read more here.
Keywords: hydroquinone dimethylamino; dimethylamino; methyl hydroquinone; reaction bis ... See more keywords
The proton sponge 1,8-bis(dimethylamino)naphthalene: The quicker-picker-upper also for s-block metal cations?
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DOI: 10.1016/j.cplett.2021.138735
Abstract: Abstract 1,8-bis-(dimethylamino)-naphthalene, the first ever reported proton sponge, has been snatching much attention with its spectacular proton affinity (PA) for decades. This manuscript discusses the affinities of DMAN towards s-block metal ions Li+, Na+, K+,… read more here.
Keywords: dimethylamino naphthalene; block metal; sponge; proton sponge ... See more keywords
Atomic layer deposition of Cu(i) oxide films using Cu(ii) bis(dimethylamino-2-propoxide) and water.
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DOI: 10.1039/c6dt02572b
Abstract: To grow films of Cu2O, bis-(dimethylamino-2-propoxide)Cu(ii), or Cu(dmap), is used as an atomic layer deposition precursor using only water vapor as a co-reactant. Between 110 and 175 °C, a growth rate of 0.12 ± 0.02… read more here.
Keywords: dimethylamino propoxide; oxide films; atomic layer; layer deposition ... See more keywords
Investigation of the full reversal of selectivity in the reaction of aniline with 1,3-dichloro-1,3-bis(dimethylamino)vinamidinium salts
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DOI: 10.1039/c7nj03442c
Abstract: The addition of aniline, even in excess, to a solution of 1,3-dichloro-1,3-bis(dimethylamino)vinamidinium salt in the presence of triethylamine invariably leads to the formation of 2,4-bis(dimethylamino)quinoline. Conversely, delaying the addition of the base leads to the… read more here.
Keywords: bis dimethylamino; dichloro bis; dimethylamino; dimethylamino vinamidinium ... See more keywords
Catalytic Aminomethylation of Aminobenzamides with Bis(N,N-dimethylamino)methane and Carbamides
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DOI: 10.1134/s1070363219020063
Abstract: An effective method was developed for the synthesis of acyclic aniline derivatives bearing carbamide fragments by the reaction of carbamides with ortho-, meta-, and para-aminobenzamides and bis(N,N-dimethylamino) methane in the presence of NiCl2·6H2O and SmCl3·6H2O… read more here.
Keywords: dimethylamino methane; catalytic aminomethylation; bis dimethylamino; aminobenzamides bis ... See more keywords
Catalytic Cycloaminomethylation of Aminobenzamides with 1,3-Bis[dimethylamino(methoxy)methyl]thiourea
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DOI: 10.1134/s1070363219030022
Abstract: Efficient methods of the synthesis of cyclophanes containing the thiourea moiety via the reaction of o-, m-, and p-aminobenzamides with 1,3-bis(dimethylaminomethyl)thiourea or 1,3-bis(methoxymethyl)thiourea using NiCl2·6H2O and SmCl3·6H2O as catalysts have been developed. read more here.
Keywords: cycloaminomethylation aminobenzamides; methoxy methyl; catalytic cycloaminomethylation; dimethylamino methoxy ... See more keywords
Synthesis of Optically and Redox Active Polyenaminones from Diamines and α,α’-Bis[(dimethylamino)methylidene]cyclohexanediones
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DOI: 10.3390/polym14194120
Abstract: New oligo- and polyenaminones with Mw ~ 7–50 KDa were prepared in high yields by transaminative amino-enaminone polymerization of regioisomeric bis[(dimethylamino)methylidene]cyclohexanediones with alkylene and phenylenediamines. The polymers obtained are practically insoluble in aqueous and organic… read more here.
Keywords: synthesis optically; bis dimethylamino; methylidene cyclohexanediones; dimethylamino methylidene ... See more keywords
Symmetry/Asymmetry of the NHN Hydrogen Bond in Protonated 1, 8-Bis(dimethylamino)naphthalene
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DOI: 10.3390/sym12111924
Abstract: Experimental and theoretical results are presented based on vibrational spectra and motional dynamics of 1,8-bis(dimethylamino)naphthalene (DMAN) and its protonated forms (DMANH+ and the DMANH+ HSO4− complex). The studies of these compounds have been performed in… read more here.
Keywords: bis dimethylamino; symmetry asymmetry; asymmetry nhn; dimethylamino naphthalene ... See more keywords
1,8-Bis(dimethylamino)naphthyl-2-ketimines: Inside vs outside protonation
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DOI: 10.3762/bjoc.14.273
Abstract: The structure and protonation behaviour of four ortho-arylketimines of 1,8-bis(dimethylamonio)naphthalene with a different number of methoxy groups in an aromatic substituent were investigated in solution by NMR (acetone, DMSO, MeCN), in solid state by X-ray… read more here.
Keywords: inside outside; naphthyl ketimines; ketimines inside; protonation ... See more keywords