P⋯O noncovalent conformational locks for constructing highly planar Bis(diphenylphosphanyl) Bi(benzofurano)
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DOI: 10.1016/j.dyepig.2020.108820
Abstract: Abstract Bis(diphenylphosphanyl) bi(benzofurano) (BBFP) and Bis(diphenylphosphanyl) bi(benzothiophene) (BBTP) were synthesized by the reaction of dilithio(benzothienylbenzofuran) or dilithio(benzothienylbenzothiophene) with Diphenylphosphinic chloride, then reduced with trichlorosilane to afford the target. Optical and electrochemical measurements of the products… read more here.
Keywords: conformational locks; noncovalent conformational; bis; bis diphenylphosphanyl ... See more keywords
Crystal structure of bromidopentakis(tetrahydrofuran-κO)magnesium bis[1,2-bis(diphenylphosphanyl)benzene-κ2 P,P′]cobaltate(−1) tetrahydrofuran disolvate
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DOI: 10.1107/s2056989019001671
Abstract: The reduction of CoBr2 by the Grignard reagent p-tolylmagnesium bromide in the presence of 1,2-bis(diphenylphosphanyl)benzene (dbpz) resulted in the d 10, formally Co−1 anion, [Co(dpbz)2]−. The crystal structure of the [MgBr(THF)5]+ (THF is tetrahydrofuran) salt… read more here.
Keywords: bis diphenylphosphanyl; bis; diphenylphosphanyl benzene; crystal structure ... See more keywords