Nickel bis(dithiolene) complexes for electrocatalytic hydrogen evolution: A computational study
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.03.007
Abstract: Abstract The substituent effect of dithiolene ligand on electrocatalytic activity of Ni bis(dithiolene) towards hydrogen evolution reaction (HER) are thoroughly explored with computational methods. A series of differently substituted dithiolene ligands are compared and evaluated.… read more here.
Keywords: nickel bis; hydrogen evolution; bis dithiolene; dithiolene ... See more keywords
Redox-Active Covalent Organic Frameworks with Nickel-Bis(dithiolene) Units as Guiding Layers for High-Performance Lithium Metal Batteries.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01996
Abstract: Combining the chemistry of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) can bring new opportunities for the design of advanced materials with enhanced tunability and functionality. Herein, we constructed two COFs based on Ni-bis(dithiolene)… read more here.
Keywords: covalent organic; organic frameworks; taa; bis dithiolene ... See more keywords
Ambipolar Nickel Dithiolene Complex Semiconductors: From One- to Two-Dimensional Electronic Structures Based upon Alkoxy Chain Lengths.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08015
Abstract: Air-stable single-component ambipolar organic semiconductors that conduct both holes and electrons are highly desired but have been rarely realized. Neutral nickel bis(dithiolene) complexes are promising candidates that fulfill the stringent electronic requirements of shallow HOMO… read more here.
Keywords: nickel bis; dithiolene; air; effective intermolecular ... See more keywords
A computational study of photonic materials based on Ni bis(dithiolene) fused with benzene, possessing gigantic second hyperpolarizabilities
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Materials Chemistry C"
DOI: 10.1039/c7tc05047j
Abstract: We propose a family of photonic materials based on nickel bis(dithiolene) [NiBDT] and benzene (B). Linear and planar oligomers of 1D and 2D polymers, together with several rich π-electron linkers (e.g. C14H8, C24H8, and C4O2H4),… read more here.
Keywords: photonic materials; second hyperpolarizability; materials based; bis dithiolene ... See more keywords
Two-dimensional π-conjugated metal bis(dithiolene) nanosheets as promising electrocatalysts for carbon dioxide reduction: a computational study
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Chemistry A"
DOI: 10.1039/c9ta02271f
Abstract: Two-dimensional π-conjugated metal bis(dithiolene) nanosheets exhibit high carbon dioxide reduction electrocatalytic activity. read more here.
Keywords: dithiolene nanosheets; dimensional conjugated; conjugated metal; bis dithiolene ... See more keywords
Hydrogen bonding interactions in single component molecular conductors based on metal (Ni, Au) bis(dithiolene) complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt00960a
Abstract: Introduction of hydrogen bonding (HB) interactions in single component conductors derived from nickel and gold bis(dithiolene) complexes is explored with the 2-alkylthio-1,3-thiazole-4,5-dithiolate (RS-tzdt) with R = CH2CH2OH through the preparation of the neutral [Ni(HOEtS-tzdt)2]0 (closed-shell)… read more here.
Keywords: bis dithiolene; hoets tzdt; hydrogen bonding; dithiolene complexes ... See more keywords
Conducting chiral nickel(ii) bis(dithiolene) complexes: structural and electron transport modulation with the charge and the number of stereogenic centres
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Materials Chemistry C"
DOI: 10.1039/d1tc00439e
Abstract: Nickel(II) bis(dithiolene) complexes can provide crystalline conducting materials either in their monoanionic or neutral forms. Here we show that the use of chiral dithiolene ligands with one or two stereogenic centres, together with variation of… read more here.
Keywords: nickel bis; dddt; bis dithiolene; stereogenic centres ... See more keywords
Covalent organic frameworks with Ni-Bis(dithiolene) and Co-porphyrin units as bifunctional catalysts for Li-O2 batteries
Sign Up to like & getrecommendations! Published in 2023 at "Science Advances"
DOI: 10.1126/sciadv.adf2398
Abstract: The rational design of efficient and stable catalysts for the oxygen reduction reaction and oxygen evolution reaction (ORR/OER) is the key to improving Li-O2 battery performance. Here, we report the construction of ORR/OER bifunctional cathode… read more here.
Keywords: organic frameworks; dithiolene porphyrin; frameworks bis; bis dithiolene ... See more keywords