Bis-Imidazole Methane Ligated Ruthenium(II) Complexes: Synthesis, Characterization, and Catalytic Activity for Hydrogen Production from Formic Acid in Water.
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DOI: 10.1021/acs.inorgchem.1c01784
Abstract: A series of half sandwich arene-ruthenium complexes [(η6-arene)RuCl(κ2-L)]+ ([Ru]-1-[Ru]-10) containing bis-imidazole methane-based ligands {4,4'-(phenylmethylene)bis(2-ethyl-5-methyl-1H-imidazole)} (L1), {4,4'-((4-methoxyphenyl)methylene)bis(2-ethyl-5-methyl-1H-imidazole)} (L2), {4,4'-((2-methoxyphenyl)methylene)bis(2-ethyl-5-methyl-1H-imidazole)} (L3), {4,4'-((4-chlorophenyl)methylene)bis(2-ethyl-5-methyl-1H-imidazole)} (L4), and {4,4'-((2-chlorophenyl)methylene)bis(2-ethyl-5-methyl-1H-imidazole)} (L5) are synthesized. The synthesized and purified complexes ([Ru]-1-[Ru]-10) are further employed… read more here.
Keywords: bis imidazole; ethyl methyl; bis; methyl imidazole ... See more keywords
3,3′-(Phenylmethylene)bis(1-ethyl-3,4-dihydro-1H-2,1-benzothiazine-2,2,4-trione): single-crystal X-ray diffraction study, quantum-chemical calculations and Hirshfeld surface analysis
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DOI: 10.1107/s2056989023002505
Abstract: The tautomeric form of 3,3′-(phenylmethylene)bis(1-ethyl-3,4-dihydro-1H-2,1-benzothiazine-2,2,4-trione) with potential antimicrobial, analgesic, and anti-inflammatory activity was studied. read more here.
Keywords: ethyl dihydro; benzothiazine trione; bis ethyl; phenylmethylene bis ... See more keywords