Gold-Induced Desulfurization in a Bis(ferrocenyl) Alkane Dithiol
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DOI: 10.1021/acs.organomet.9b00175
Abstract: Thiol-modified ferrocenes on gold have been archetypical model systems for many fundamental charge transfer and other studies, since both thiol-gold and ferrocene redox chemistry are considered to be well-understood. Thus unexpectedly, we found that for… read more here.
Keywords: dithiol; desulfurization bis; gold induced; bis ferrocenyl ... See more keywords
Bis-Ferrocenyl-Pyridinediimine Trinuclear Mixed-Valent Complexes with Metal-Binding Dependent Electronic Coupling: Synthesis, Structures, and Redox-Spectroscopic Characterization.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c10015
Abstract: A family of metal dichloride complexes having a bis-ferrocenyl-substituted pyridinediimine ligand was systematically synthesized ((Fc2PDI)MCl2, M = Mg, Zn, Fe, and Co) and characterized crystallographically, spectroscopically, electrochemically, and computationally. Electronic coupling between the ligand ferrocene… read more here.
Keywords: electronic coupling; metal; bis ferrocenyl; pyridinediimine ... See more keywords
Mechanistic investigations and molecular properties of 1,2-bis(ferrocenyl)dimetallenes including group 14 elements
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DOI: 10.1039/c7ra04935h
Abstract: The molecular properties and reactive activities of the d-π conjugated (E)-Tip(Fc)E14E14(Fc)Tip (1-C, 1-Si, 1-Ge, 1-Sn, and 1-Pb) systems possessing the E14E14 unit were explored using density functional theory (M06-2X/Def2-SVPD). The theoretical investigations on the basis… read more here.
Keywords: investigations molecular; molecular properties; mechanistic investigations; group ... See more keywords
Helical versus Flat Bis-Ferrocenyl End-Capped Peptides: The Influence of the Molecular Skeleton on Redox Properties
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27186128
Abstract: Despite the fact that peptide conjugates with a pendant ferrocenyl (Fc) have been widely investigated, bis-ferrocenyl end-capped peptides are rarely synthetized. In this paper, in addition to the full characterization of the Fc-CO-[L-Dap(Boc)]n-NH-Fc series, we… read more here.
Keywords: bis; ferrocenyl end; end capped; bis ferrocenyl ... See more keywords