Exceptionally high molecular weight linear polyethylene by using N,N,N′‐ Co catalysts appended with a N′ ‐2,6‐bis{di(4‐fluorophenyl)methyl}‐4‐nitrophenyl group
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DOI: 10.1002/aoc.5157
Abstract: The bis(arylimino)pyridines, 2-[CMeN{2,6-{(4-FC6H4)2CH}2-4-NO2}]-6-(CMeNAr)C5H3N (Ar = 2,6-Me2C6H3 L1, 2,6-Et2C6H3 L2, 2,6-i-Pr2C6H3 L3, 2,4,6-Me3C6H2 L4, 2,6-Et2-4-MeC6H2 L5), each containing one N'-2,6-bis{di(4-fluorophenyl)methyl}-4-nitrophenyl group, have been synthesized by two successive condensation reactions from 2,6-diacetylpyridine. Their subsequent treatment with anhydrous… read more here.
Keywords: methyl nitrophenyl; fluorophenyl methyl; bis; bis fluorophenyl ... See more keywords
Magnetic resonance and mass spectrometric characterization and conformational analysis of α,α-bis(4-fluorophenyl)-β-methyl-1H-imidazole-1-ethanol
Sign Up to like & getrecommendations! Published in 2020 at "Spectroscopy Letters"
DOI: 10.1080/00387010.2020.1843497
Abstract: Abstract A complete multinuclear magnetic resonance characterization of α,α-bis(4-fluorophenyl)-β-methyl-1H-imidazole-1-ethanol (a representative carbinoloimidazole topical anti-inflammatory agent) is presented, the first such assignment of a compound with diastereotopic fluorophenyl rings. The relative orientation of the 4-fluorophenyl rings… read more here.
Keywords: fluorophenyl methyl; magnetic resonance; fluorophenyl; spectroscopy ... See more keywords
Crystal structure, Hirshfeld surface analysis and DFT study of (5E,5′E,6Z,6′Z)-6,6′-[ethane-1,2-diylbis(azanylylidene)]bis{5-[2-(4-fluorophenyl)hydrazono]-3,3-dimethylcyclohexanone} 2.5-hydrate
Sign Up to like & getrecommendations! Published in 2023 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989023001895
Abstract: The title compound was obtained by the condensation of ethylenediamine and (5E,5E,6Z,6Z)-6,6-[ethane-1,2-diylbis(azanylylidene)]bis{5-[2-(4-fluorophenyl)hydrazono)-3,3-dimethylcyclohexanone} in ethanol and crystallized as a 1:2.5 hydrate containing two different conformers stabilized by intramolecular N—H⋯N and linked by O—H⋯O (involving the water… read more here.
Keywords: ethane diylbis; azanylylidene bis; diylbis azanylylidene; bis fluorophenyl ... See more keywords