Insertion Reaction of Me3SiN3 with Bis(germylene).
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02252
Abstract: Herein, we describe the redox reaction of bis(germylene) PhC(NtBu)2Ge-Ge(NtBu)2CPh with different equivalents of Me3SiN3 affording two distinct products. The reaction of Me3SiN3 with bis-germylene in a 1:1 molar ratio results in compound 1 at -78… read more here.
Keywords: bis germylene; reaction me3sin3; germylene;
Carbene stabilized interconnected bis-germylene and its silicon analogue with small methyl substituents.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01796k
Abstract: The cyclic alkyl(amino) carbene (cAAC) [:C{N-C6H3(2,6-IPr2)}(CMe2)2CH2] stabilized MeGeGeMe has been isolated in the molecular form with composition (cAAC)MeGe-GeMe(cAAC) (1) at room temperature. Compound 1 was synthesized from the reduction of MeGeCl3 using three equivalents of… read more here.
Keywords: bis germylene; stabilized interconnected; silicon; caac ... See more keywords