Bis-N-Heterocyclic Carbene Complexes of Coinage Metals Containing Four Naphthalimide Units: A Structure-Emission Properties Relationship Study.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01302
Abstract: Naphthalimide derivatives provide highly versatile self-assembled systems and aggregated forms with fascinating emission properties that make them potential candidates for many applications such as bioimaging and sensing. Although various aggregated species of naphthalimide derivatives have… read more here.
Keywords: bis heterocyclic; naphthalimide units; emission properties; heterocyclic carbene ... See more keywords
Extreme g-Tensor Anisotropy and Its Insensitivity to Structural Distortions in a Family of Linear Two-Coordinate Ni(I) Bis-N-heterocyclic Carbene Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02413
Abstract: We report a new series of homoleptic Ni(I) bis-N-heterocyclic carbene complexes with a range of torsion angles between the two ligands from 68° to 90°. Electron paramagnetic resonance measurements revealed a strongly anisotropic g-tensor in… read more here.
Keywords: carbene complexes; extreme tensor; bis heterocyclic; heterocyclic carbene ... See more keywords
“Dynamical Docking” of Cyclic Dinuclear Au(I) Bis-N-heterocyclic Complexes Facilitates Their Binding to G-Quadruplexes
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c03041
Abstract: With the aim to improve the design of metal complexes as stabilizers of noncanonical DNA secondary structures, namely, G-quadruplexes (G4s), a series of cyclic dinuclear Au(I) N-heterocyclic carbene complexes based on xanthine and benzimidazole ligands… read more here.
Keywords: cyclic dinuclear; dna; docking cyclic; dinuclear bis ... See more keywords
The Influence of para Substituents in Bis(N-Heterocyclic Carbene) Palladium Pincer Complexes for Electrocatalytic CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02213
Abstract: The effect of modifying the pyridyl para position of lutidine-linked bis(N-heterocyclic carbene) Pd pincer complexes is studied both experimentally (R = OMe, H, Br, and COOR) and computationally, showing a strong effect on the first… read more here.
Keywords: reduction; bis heterocyclic; heterocyclic carbene; para ... See more keywords
Air and Moisture Stable para- and ortho-Quinodimethane Derivatives Derived from bis-N-Heterocyclic Olefins.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03993
Abstract: Herein we report the development of a new methodology for the synthesis of various quinodimethane derivatives under two-electron oxidation of bis-N-heterocyclic olefins linked by different π-conjugated aromatic spacers. In case of para- and ortho-phenylene bridge,… read more here.
Keywords: air moisture; quinodimethane derivatives; para ortho; heterocyclic olefins ... See more keywords
Metalloradical intermediates in electrocatalytic reduction of CO2 to CO: Mn versus Re bis-N-heterocyclic carbene pincers.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/c9dt04691g
Abstract: This work examines the relative reactivities of ReI and MnI tricarbonyl pyridine-2,6-bis-N-heterocyclic carbene pincers M(CO)3CNCBnX (M = Re, Mn and X = Cl and Br) towards catalysis for the electrochemical conversion of CO2 to CO.… read more here.
Keywords: reduction; bis heterocyclic; carbene pincers; co2 ... See more keywords