5-(Chloromethyl)Furfural as a Potential Source for Continuous Hydrogenation of 5-(Hydroxymethyl)Furfural to 2,5-Bis(Hydroxymethyl)Furan.
Sign Up to like & getrecommendations! Published in 2022 at "ChemPlusChem"
DOI: 10.1002/cplu.202200272
Abstract: Invited for this month's cover is the group of Prof. Young-Woong Suh at Hanyang University, Republic of Korea. The cover picture depicts the conceptual design of plastic manufacture starting from 5-(chloromethyl)furfural (CMF) generated from raw… read more here.
Keywords: bis hydroxymethyl; hydrogenation; hydroxymethyl furfural; hydroxymethyl furan ... See more keywords
Biocatalytic Reduction of HMF to 2,5-Bis(hydroxymethyl)furan by HMF-Tolerant Whole Cells.
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DOI: 10.1002/cssc.201601426
Abstract: Catalytic upgrading of 5-hydroxymethylfurfural (HMF), an important biobased platform chemical for high-value products, is currently of great interest. In this work, a new highly HMFtolerant yeast strain-Meyerozyma guilliermondii SC1103 was isolated, and biocatalytic reduction of… read more here.
Keywords: reduction; reduction hmf; biocatalytic reduction; hmf ... See more keywords
Enantiopure vicinally trisubstituted all-cis-bis(hydroxymethyl)-cyclopentenols and their derivatives
Sign Up to like & getrecommendations! Published in 2018 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2018.09.033
Abstract: Oxidations of {(1R,4R,5S)-2-[tert-butyl(dimethyl)silyloxy-methyl]-4-(trimethylsilyl)cyclopent-2-en-1-yl}methanol with m-chloroperoxybenzoic acid (mCPBA) and dimethyldioxirane were studied. In the case of mCPBA, an allylicic alcohol expected according to the protodesilylation mechanism and an anomalous product of 1,2-migration of the Me3Si group… read more here.
Keywords: enantiopure vicinally; cis bis; vicinally trisubstituted; trisubstituted cis ... See more keywords
Biobased 2,5-Bis(hydroxymethyl)furan as a Versatile Building Block for Sustainable Polymeric Materials
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DOI: 10.1021/acsomega.2c07629
Abstract: Furanic polymers, currently mainly represented by polyethylene 2,5-furandicarboxylate (PEF), also known as polyethylene furanoate, have a fantastic potential to replace fossil-based polymers: for example, polyethylene terephthalate (PET). While 2,5-furandicarboxylic acid (FDCA), a precursor of PEF,… read more here.
Keywords: bhmf; bis hydroxymethyl; biobased bis; hydroxymethyl furan ... See more keywords
Eco-Friendly Enzymatic Production of 2,5-Bis(hydroxymethyl)furan Fatty Acid Diesters, Potential Biodiesel Additives
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b01206
Abstract: Due to the increasing need for greener and sustainable alternatives to fossil-based industrial chemicals and products, development of efficient synthesis of biomass-based platform chemicals is an attractive goal. 5-Hydroxymethylfurfural (HMF) derived 2,5-bis(hydroxymethyl)furan (BHMF) is one… read more here.
Keywords: production; biodiesel; eco friendly; hydroxymethyl furan ... See more keywords
Production of Hydroxymethylfurfural Derivatives From Furfural Derivatives via Hydroxymethylation
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Bioengineering and Biotechnology"
DOI: 10.3389/fbioe.2022.851668
Abstract: Hydroxymethylfurfural (HMF) derivatives such as 2,5-bis(hydroxymethyl)furan (BHMF) and furandicarboxylic acid (FDCA) are promising alternative of fossil-based diols and dicarboxylic acids for synthesis of polyesters such as polyethylene terephthalate (PET). However, high cost for preparing HMF… read more here.
Keywords: furfural derivatives; hydroxymethylation; bis hydroxymethyl; production hydroxymethylfurfural ... See more keywords
Copper(II) 2,2-Bis(Hydroxymethyl)Propionate Coordination Compounds with Hexamethylenetetramine: From Mononuclear Complex to One-Dimensional Coordination Polymer
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DOI: 10.3390/molecules26113358
Abstract: Three new copper coordination compounds derived from 2,2-bis(hydroxymethyl)propionic acid (dmpa) and hexamethylenetetramine (hmta) were obtained and their crystal structures were determined. The stoichiometry of the reagents applied in the syntheses reflects the metal to ligand… read more here.
Keywords: coordination compounds; coordination; coordination polymer; hmta ... See more keywords
Tethered Blatter Radical for Molecular Grafting: Synthesis of 6-Hydroxyhexyloxy, Hydroxymethyl, and Bis(hydroxymethyl) Derivatives and Their Functionalization
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DOI: 10.3390/molecules27041176
Abstract: Synthetic access to 7-CF3-1,4-dihydrobenzo[e][1,2,4]triazin-4-yl radicals containing 4-(6-hydroxyhexyloxy)phenyl, 4-hydroxymethylphenyl or 3,5-bis(hydroxymethyl)phenyl groups at the C(3) position and their conversion to tosylates and phosphates are described. The tosylates were used to obtain disulfides and an azide with… read more here.
Keywords: tethered blatter; bis hydroxymethyl; hydroxymethyl; radical molecular ... See more keywords