Chelating Bis-silylenes As Powerful Ligands To Enable Unusual Low-Valent Main-Group Element Functions.
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DOI: 10.1021/acs.accounts.2c00763
Abstract: ConspectusSilylenes are divalent silicon species with an unoccupied 3p orbital and one lone pair of electrons at the SiII center. Owing to the excellent σ-donating ability of amidinato-based silylenes, which stems from the intramolecular imino-N… read more here.
Keywords: group; bis nhsi; main group; low valent ... See more keywords