Synthesis, Characterization, and Catalytic Study of Amine-Bridged Bis(phenolato) Co(II) and Co(II/III)-M(I) Complexes (M = K or Na).
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DOI: 10.1021/acs.inorgchem.1c01542
Abstract: Co(II) complexes 1-3 bearing amine-bridged bis(phenolato) complexes have been synthesized through reactions of bis(phenols) with CoCl2 or Co(OAc)2. Oxidation of the Co(II) complex with air resulted in partial oxidation, generating mixed valence Co(II/III) complexes 4… read more here.
Keywords: iii; amine bridged; bridged bis; iii complexes ... See more keywords
Rare-earth/zinc heterometallic complexes containing both alkoxy-amino-bis(phenolato) and chiral salen ligands: synthesis and catalytic application for copolymerization of CO2 with cyclohexene oxide.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00064j
Abstract: Ten rare-earth/zinc heterometallic complexes containing both alkoxy-amino-bis(phenolato) and chiral salen ligands were synthesized from the reactions of alkoxy-amino-bis(phenolato) rare-earth complexes with chiral salen zinc complexes via ligand redistribution and THF disassociation. Six of them were… read more here.
Keywords: zinc; heterometallic complexes; rare earth; alkoxy amino ... See more keywords