Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water
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DOI: 10.1039/d1ra09136k
Abstract: A highly efficient and mild palladium-catalyzed hydroboration of unactivated internal alkynes in water is described. Both aryl- and alkyl-substituted alkynes proceeded smoothly within the reaction time to afford the desired vinylboronates in moderate to high… read more here.
Keywords: bis pinacolato; pinacolato diboron; catalyzed hydroboration; palladium catalyzed ... See more keywords
α,β-Enone Borylation by Bis(Pinacolato)Diboron Catalyzed by Cu3(BTC)2 Using Cesium Carbonate as a Base
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DOI: 10.3390/nano11061396
Abstract: Cu3(BTC)2 (BTC: 1,3,5-benzenetricarboxylate) as a heterogeneous catalyst in the presence of cesium carbonate as a base is reported for the borylation of α,β-conjugated enones by bis(pinacolato)diboron (B2pin2). According to the hot-filtration test, Cu3(BTC)2 is acting… read more here.
Keywords: cesium carbonate; carbonate base; btc; cu3 btc ... See more keywords