From Pincer to Paddlewheel: C-H and C-S Bond Activation at Bis(2-pyridylthio)methane by Palladium(II).
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b03568
Abstract: The bis(2-pyridylthio)methanidopalladium(II) pincer complex (1), containing a Pd-C bond, was obtained from the reaction of bis(2-pyridylthio)methane (H2L) with palladium(II) acetate in toluene under reflux. When palladium(II) trifluoroacetate was used, H2L reacted to generate the tetrakis(pyridine-2-thiol)palladium(II)… read more here.
Keywords: pincer; palladium; pyridylthio methane; bis pyridylthio ... See more keywords
Synthesis of bis(2-pyridylthio)methyl zinc hydride and catalytic hydrosilylation and hydroboration of CO2.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06963b
Abstract: The reactions of bis(2-pyridylthio)methane with Me2Zn and Zn[N(SiMe3)2]2 afford [Bptm]ZnMe and [Bptm]ZnN(SiMe3)2, thereby providing access to a variety of other [Bptm]ZnX derivatives, including the zinc hydride complex [Bptm]ZnH, which serves as a catalyst for the… read more here.
Keywords: bis pyridylthio; hydrosilylation hydroboration; bptm; zinc hydride ... See more keywords