Articles with "bis secondary" as a keyword



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Rhodium-Catalyzed Isomerization of a Bis(secondary phosphine) to an Unsymmetrical Diphosphine via P–C Cleavage and P–P and C–H Bond Formation

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Published in 2017 at "Organometallics"

DOI: 10.1021/acs.organomet.7b00515

Abstract: To develop Rh-catalyzed dehydrocoupling for stereocontrolled synthesis of P–P bonds, we prepared potential intermediates, chiral rhodium phosphine-phosphido complexes, and investigated their stoichiometric and catalytic transformations. Treatment of [Rh(diphos*)(COD)][X] with the bis(secondary phosphine) IsHPCH2PHIs (1, Is… read more here.

Keywords: phosphine; bis secondary; unsymmetrical diphosphine; secondary phosphine ... See more keywords