Diastereoselective Synthesis and Two-Step Photocleavage of Ruthenium Polypyridyl Complexes Bearing a Bis(thioether) Ligand
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DOI: 10.1021/acs.inorgchem.9b01669
Abstract: Thioethers are good ligands for photoactivatable ruthenium(II) polypyridyl complexes, as they form thermally stable complexes that are prone to ligand photosubstitution. Here, we introduce a novel symmetric chelating bis(thioether) ligand scaffold, based on 1,3-bis(methylthio)-2-propanol (4)… read more here.
Keywords: ruthenium; bis thioether; ruthenium polypyridyl; bis ... See more keywords