Iridium(III) bis(thiophosphinite) pincer complexes: synthesis, ligand activation and applications in catalysis.
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DOI: 10.1039/d2dt01633h
Abstract: Iridium(III) bis(thiophosphinite) complexes of the type [(RPSCSPR)Ir(H)(Cl)(py)] (RPSCSPR = κ3-(2,6-SPR2)C6H3) (R = tBu, iPr, Ph) can be prepared from the ligand precursors 1,3-(SPR2)C6H4 by C-H activation at Ir using [Ir(COE)2Cl]2 or [Ir(COD)Cl]2. Optimisation of the… read more here.
Keywords: bis thiophosphinite; ligand activation; presence; iridium iii ... See more keywords