Synthesis, Crystal Structure, Anion Sensing Applications and DFT Studies of (E)-2-[(3,5-Bis(trifluoromethyl)phenylimino)methyl]-4-chlorophenol
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Crystallography"
DOI: 10.1007/s10870-018-0758-7
Abstract: We report the synthesis and characterization, colorimetric anion sensors properties, density functional theory (DFT) calculation studies of a Schiff base (E)-2-[(3,5-bis(trifluoromethyl)phenylimino)methyl]-4-chlorophenol. The molecular structure of the title compound was experimentally determined using X-ray single-crystal data… read more here.
Keywords: trifluoromethyl phenylimino; methyl chlorophenol; anion; phenylimino methyl ... See more keywords
Measurements of the solubility parameter and enthalpies of vaporization in N-alkyl-pyridinium bis((trifluoromethyl)sulfonyl)imide ([CnPY][NTF2], n = 4,6,8) ionic liquid
Sign Up to like & getrecommendations! Published in 2019 at "Fluid Phase Equilibria"
DOI: 10.1016/j.fluid.2018.12.014
Abstract: Abstract Some thermodynamic and physicochemical properties of N-alkyl-pyridinium bis((trifluoromethyl)sulfonyl)imide ([CnPY][NTF2], n = 4, 6, 8) ionic liquids (ILs) were investigated through inverse gas chromatography at temperatures from 333.15 K to 373.15 K. A total of 23 solvents were used… read more here.
Keywords: sulfonyl imide; alkyl pyridinium; trifluoromethyl sulfonyl; pyridinium bis ... See more keywords
Exploring Arylazo-3,5-Bis(trifluoromethyl)pyrazole Switches
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04984
Abstract: Arylazopyrazoles stand out among the azoheteroarene photoswitches due to their excellent properties in terms of stability of the least stable isomer and conversion between isomers, leading to their use in several interesting applications. We report… read more here.
Keywords: trifluoromethyl; bis trifluoromethyl; trifluoromethyl pyrazole; exploring arylazo ... See more keywords
Photoluminescence and electroluminescence of an iridium(III) complex with 2′,6′-bis(trifluoromethyl)-2,4′-bipyridine and 2-(5-phenyl-1,3,4-thiadiazol-2-yl)phenol ligands
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c7nj00163k
Abstract: Using electron transport units containing 2′,6′-bis(trifluoromethyl)-2,4′-bipyridine as the main ligand and 2-(5-phenyl-1,3,4-thiadiazol-2-yl)phenol as the ancillary ligand, an iridium(III) complex (Ir(BTBP)2TDZ) was synthesized, characterized and investigated in detail. The greenish yellow photoluminescence spectrum peaks at 551… read more here.
Keywords: phenyl thiadiazol; iridium iii; iridium; bis trifluoromethyl ... See more keywords
Adducts of triangular silver(i) 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03344k
Abstract: π-Acidic triangular silver(i) 3,5-bis(trifluoromethyl)pyrazolate (Ag3pz3) can form 1 : 1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by π-π stacking and, therefore,… read more here.
Keywords: silver bis; interaction model; bis trifluoromethyl; weak interaction ... See more keywords
Transmembrane fluoride anion transport by meso-3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc02032k
Abstract: Meso-3,5-bis(trifluoromethyl)phenyl picket calix[4]pyrrole 1 displays excellent fluoride anion transport activity across artificial lipid bilayers showing EC50 = 2.15 μM (at 450 s in EYPC vesicle) with high fluoride over chloride ion selectivity. The high fluoride… read more here.
Keywords: meso bis; bis trifluoromethyl; trifluoromethyl phenyl; picket calix ... See more keywords
A New Copper Ionophore N1, N3-Bis [[3,5-Bis(Trifluoromethyl)Phenyl] Carbamothioyl] Isophtalamide for Potentiometric Sensor
Sign Up to like & getrecommendations! Published in 2018 at "Sains Malaysiana"
DOI: 10.17576/jsm-2018-4711-08
Abstract: A copper ion sensor based on a new bis-thiourea compound N1,N3-bis[[3,5-bis(trifluoromethyl)phenyl]carbamothioyl]isophthalamide (or TPC) as neutral carrier was investigated. The immobilization of the TPC into poly(n-butyl acrylate) (pBA) membrane via drop casting and the sensor was… read more here.
Keywords: copper ion; bis trifluoromethyl; bis bis; bis ... See more keywords
Using Choline Chloride-Based DESs as Co-Solvent for 3,5-Bis(trifluoromethyl) Acetophenone Bioreduction with Rhodococcus erythropolis XS1012
Sign Up to like & getrecommendations! Published in 2019 at "Catalysts"
DOI: 10.3390/catal10010030
Abstract: (S)-3,5-Bistrifluoromethylphenyl ethanol((S)-BTPE) is a key pharmaceutical intermediate of the NK-1 receptor antagonist. The asymmetric bioreduction of 3,5-bis(trifluoromethyl) acetophenone (BTAP) to (S)-BTPE using Rhodococcus erythropolis XS1012 has been established in a phosphate buffer system. To overcome… read more here.
Keywords: choline chloride; system; bis trifluoromethyl; trifluoromethyl acetophenone ... See more keywords
A Synthetic Curcuminoid Analog, (2E,6E)-2,6-bis(2-(trifluoromethyl)benzylidene)cyclohexanone, Ameliorates Impaired Wound Healing in Streptozotocin-Induced Diabetic Mice by Increasing miR-146a
Sign Up to like & getrecommendations! Published in 2020 at "Molecules"
DOI: 10.3390/molecules25040920
Abstract: The impairment in diabetic wound healing represents a significant clinical problem, with no efficient targeted treatments for these wound disorders. Curcumin is well confirmed to improve diabetic wound healing, however, its low bioavailability and poor… read more here.
Keywords: wound healing; mir 146a; bis trifluoromethyl; trifluoromethyl benzylidene ... See more keywords
Systematic Study on Nonlinear Optical Chromophores with Improved Electro-Optic Activity by Introducing 3,5-Bis(trifluoromethyl)benzene Derivative Isolation Groups into the Bridge
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28020488
Abstract: A series of novel chromophores A, B, C, and D, based on the julolidinyl donor and the tricyanofuran (TCF) and CF3-tricyanofuran (CF3-Ph-TCF) acceptors, have been synthesized and systematically investigated. The 3,5-bis(trifluoromethyl)benzene derivative isolation group was… read more here.
Keywords: trifluoromethyl benzene; nonlinear optical; bis trifluoromethyl; isolation ... See more keywords