Hydrophosphination-type reactivity promoted by bismuth phosphanides: scope and limitations.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00226b
Abstract: Phenyl isocyanate inserts into the Bi-P bond of the terminal phosphanide Bi(NONAr)(PCy2) (NONAr = [O(SiMe2NAr)2]2- Ar = 2,6-iPr2C6H3) to afford the κ2N,O-phosphanylcarboxamidate complex. Liberation of the hydrophosphination product from the metal is achieved by reaction… read more here.
Keywords: hydrophosphination type; bismuth phosphanides; type reactivity; hydrophosphination ... See more keywords