Manganese(i)-catalyzed access to 1,2-bisphosphine ligands
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DOI: 10.1039/d1sc06694c
Abstract: Chiral bisphosphine ligands are of key importance in transition-metal-catalyzed asymmetric synthesis of optically active products. However, the transition metals typically used are scarce and expensive noble metals, while the synthetic routes to access chiral phosphine… read more here.
Keywords: manganese catalyzed; catalyzed access; access bisphosphine; bisphosphine ... See more keywords
The Reaction Pathway Leading to Dinuclear Rhodium and Iridium Complexes from Alkyne-Containing Bisphosphine Ligands
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DOI: 10.1246/bcsj.20200036
Abstract: A mechanistic study of a series of dinuclear complexes produced by the complexation of alkyne-containing bisphosphine ligands with Ir and Rh has been performed by experimental analysis as well as d... read more here.
Keywords: pathway leading; alkyne containing; reaction pathway; bisphosphine ligands ... See more keywords