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Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c12843
Abstract: We report an asymmetric homocoupling of ortho-(iodo)arylphosphine oxides and ortho-(iodo)arylphosphonates resulting in highly enantioenriched axially chiral bisphosphine oxides and bisphosphonates. These products are readily converted to enantioenriched biaryl bisphosphines without need for chiral auxiliaries or…
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Keywords:
bisphosphobiarenes via;
synthesis axially;
optical resolution;
chiral bisphosphobiarenes ... See more keywords