Bisstibane-distibane conversion via consecutive single-electron oxidation and reduction reaction.
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DOI: 10.1039/d2cc01986h
Abstract: peri-Substituted naphthalene complexes (Trip2Pn)2Naph (Pn = Sb 1, Bi 2) were synthesised and their redox behaviour investigated. Oxidation of 1 with [Fc][BArF] (BArF = B(C6F5)4) yielded [(Trip2Sb)(TripSb)Naph][BArF] (3) containing the stibane-coordinated stibenium cation [(Trip2Sb)(TripSb)Naph]+. Subsequent… read more here.
Keywords: oxidation; distibane conversion; conversion via; via consecutive ... See more keywords