Calcium Bistriflimide-Mediated Sulfur(VI)–Fluoride Exchange (SuFEx): Mechanistic Insights toward Instigating Catalysis
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DOI: 10.1021/acs.inorgchem.2c01230
Abstract: We report a mechanistic investigation of calcium bistriflimide-mediated sulfur(VI)–fluoride exchange (SuFEx) between sulfonyl fluorides and amines. We determine the likely pre-activation resting state—a calcium bistriflimide complex with ligated amines—thus allowing for corroborated calculation of the… read more here.
Keywords: calcium; sufex; bistriflimide mediated; mediated sulfur ... See more keywords