Carbonyl o-semiqunonato rhodium complexes with diphosphine ligands. Effect of diphosphine bite angle on reactivity and dynamic processes in their coordination sphere. EPR study
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.07.001
Abstract: Abstract The bite angle of chelating diphosphines is often responsible for the activity and the selectivity of rhodium catalysts based on them. The EPR study of the composition and the structure of similar complexes with… read more here.
Keywords: epr study; rhodium; rhodium complexes; coordination sphere ... See more keywords
Wide-Bite-Angle Diphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence Applications.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00804
Abstract: We report a series of seven cationic heteroleptic copper(I) complexes of the form [Cu(P^P)(dmphen)]BF4, where dmphen is 2,9-dimethyl-1,10-phenanthroline and P^P is a diphosphine chelate, in which the effect of the bite angle of the diphosphine… read more here.
Keywords: angle diphosphine; copper complexes; copper; bite angle ... See more keywords
Photophysical Properties of Pt(II) Polypyridines with Five- versus Six-Membered Chelate Rings: Trade-Offs in Angle Strain.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00636
Abstract: This report describes the synthesis and characterization of a series of eight [Pt(NNN)X]+ complexes where the tridentate NNN ligand is (2,2'-bipyrid-6-yl)(pyrid-2-yl)sulfide (btp) or methyl(2,2'-bipyrid-6-yl)(pyrid-2-yl)amine (bmap) and X is OMe, Cl, phenylethynyl (C2Ph), or cyclohexylethynyl (C2Cy).… read more here.
Keywords: angle; six membered; angle strain; properties polypyridines ... See more keywords