Orchestrating Communications in a Three-Type Chirality Totem: Remote Control of the Chiroptical Response of a Möbius Aromatic System.
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DOI: 10.1021/jacs.9b04074
Abstract: Among the various types of chirality (central, axial, helical, planar…), that inherent to Möbius topology remains almost unex-plored, partly due to the difficulty to access Möbius compounds. Over the last decade, [28]hexaphyrins have revealed among… read more here.
Keywords: chirality; chiroptical response; bius aromatic; response bius ... See more keywords
From a Möbius-aromatic interlocked Mn2B10H10 wheel to the metal-doped boranaphthalenes M2@B10H8 and M2B5 2D-sheets (M = Mn and Fe): a molecules to materials continuum using DFT studies
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DOI: 10.1039/d2sc02244c
Abstract: The inherent tendency of BR fragments to undergo coupling is utilized to predict M2B10H10 and M2@B10H8 complexes (where M = Mn and Fe). Electronic structure analysis of Mn2B10H10 (7) shows that the metal d-orbitals stabilize… read more here.
Keywords: bius aromatic; interlocked mn2b10h10; structure; wheel ... See more keywords