Articles with "boc mediated" as a keyword



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Synthesis of the [6.6.7.5] Tetracyclic Core of Calyciphylline N via a Boc-Mediated Oxidative Dearomatization/Diels-Alder Approach.

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Published in 2022 at "Organic letters"

DOI: 10.1021/acs.orglett.2c00797

Abstract: A sequential process involving Boc-mediated oxidative dearomatization and inter/intramolecular Diels-Alder reaction was investigated. Based on an intermolecular Diels-Alder reaction and subsequently a radical 7-endo-trig type cyclization, the [6.6.7.5] tetracyclic core of Calyciphylline N was assembled. read more here.

Keywords: diels alder; oxidative dearomatization; core calyciphylline; boc mediated ... See more keywords