Radical SAM enzymes: Nature's choice for radical reactions
Sign Up to like & getrecommendations! Published in 2022 at "FEBS Letters"
DOI: 10.1002/1873-3468.14519
Abstract: Enzymes that use a [4Fe‐4S]1+ cluster plus S‐adenosyl‐l‐methionine (SAM) to initiate radical reactions (radical SAM) form the largest enzyme superfamily, with over half a million members across the tree of life. This review summarizes recent… read more here.
Keywords: radical sam; reactions radical; sam; radical reactions ... See more keywords
Hydrogen Bond Induced Green Solvent Processed High Performance Ternary Organic Solar Cells with Good Tolerance on Film Thickness and Blend Ratios
Sign Up to like & getrecommendations! Published in 2019 at "Advanced Functional Materials"
DOI: 10.1002/adfm.201902078
Abstract: For comprehensive development of organic solar cells (OSCs), some factors such as environmental stability, low cost, insensitive film thickness, component contents tolerance, and green preparation processes are equally crucial to achieve high power conversion efficiencies… read more here.
Keywords: high performance; film thickness; hydrogen bond; bond ... See more keywords
Weak Bonding and Anharmonicity in Thermoelectric ZnSb
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202401703
Abstract: The Zn─Sb binary system contains two high‐performing thermoelectric materials, namely the ordered ZnSb and the disordered Zn13Sb10. Both systems exhibit low thermal conductivity, which is speculated to originate from multicentre bonding within Zn2Sb2‐rhombi. Here, the… read more here.
Keywords: electron density; weak bonding; anharmonicity; znsb ... See more keywords
Polarizable H‐Bond Concept in Aromatic Poly(thiourea)s: Unprecedented High Refractive Index, Transmittance, and Degradability at Force to Enhance Lighting Efficiency
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202404433
Abstract: Developing transparent and highly refractive environmentally friendly polymers has not been realized yet toward sustainable optoelectronics. This work describes poly(thiourea)s (PTUs) design following a new “polarizable group synergy” concept, combining highly polarizable hydrogen bonding groups… read more here.
Keywords: poly thiourea; refractive index; bond; high refractive ... See more keywords
Dual‐Bond Confinement Enhanced Polyphosphides Adsorption and Electrochemical Kinetics in Metal Phosphides Anodes for Reversible and Stable Lithium/Sodium Storage
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202417253
Abstract: Metal phosphides exhibit high energy densities as hosts for lithium/sodium storage owing to their conversion reaction mechanism. Nevertheless, they typically suffer from inferior reversibility and cyclability because of the dissolution of polyphosphides and sluggish electrochemical… read more here.
Keywords: sodium storage; lithium sodium; dual bond; bond ... See more keywords
Recent Progress in Advanced Catalytic Strategies for C─F Bond Cleavage in Waste Refrigerants: A Review
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202420883
Abstract: The degradation of fluorinated refrigerants, known for their highly stable carbon‐fluorine (C─F) bonds, poses significant environmental and technical challenges. This review addresses these challenges by analyzing two core degradation mechanisms: molecular polarization (MP) and free… read more here.
Keywords: degradation; recent progress; bond cleavage; progress advanced ... See more keywords
Stabilized P─F Bond for Sustainable and Ultralong Life High‐Energy Lithium Batteries
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202519229
Abstract: The instability of P─F bond‐based electrolyte (PFE) under ambient conditions presents one of the biggest challenges for the production, usage, and recycling of lithium (Li) batteries. It increases the cost of battery production, decreases battery… read more here.
Keywords: battery; stabilized bond; lithium batteries; life ... See more keywords
Dynamic S→Zn Coordination Bond Engineering toward High‐Performance Mechanically Robust Organic Photovoltaics
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202520173
Abstract: While organic photovoltaics (OPVs) achieve remarkable power conversion efficiencies (PCEs) through conjugated polymer donors and non‐fullerene small‐molecule acceptors, their inherent mechanical brittleness severely limits their commercial applicability in flexible and wearable electronics. To address this… read more here.
Keywords: coordination bond; mechanically robust; performance; organic photovoltaics ... See more keywords
Breaking Bond-Strain Lockstep in Multielectron Anodes.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced materials"
DOI: 10.1002/adma.202517295
Abstract: The pervasive bond-strain negative feedback loop in multi-electron conversion-alloy anodes, where strong covalent bonds constrain lattice transformation during sodiation, induces strain accumulation and bond rupture. This results in sluggish kinetics and severe capacity decay, crippling… read more here.
Keywords: breaking bond; lockstep multielectron; strain lockstep; bond ... See more keywords
High‐Performance Room Temperature Ammonia Sensors Based on Pure Organic Molecules Featuring B‐N Covalent Bond
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202308483
Abstract: Exploring organic semiconductor gas sensors with high sensitivity and selectivity is crucial for the development of sensor technology. Herein, for the first time, a promising chemiresistive organic polymer P‐BNT based on a novel π‐conjugated triarylboron… read more here.
Keywords: organic molecules; high performance; performance room; room temperature ... See more keywords
Direct Identification of O─O Bond Formation Through Three‐Step Oxidation During Water Splitting by Operando Soft X‐ray Absorption Spectroscopy (Adv. Sci. 40/2024)
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202470244
Abstract: Direct Identification of O–O Bond Formation In article number 2401236, Wu‐Ching Chou, Shuangyin Wang, Zhiwei Hu, Chung‐Li Dong, and co‐workers report the first direct observation of O–O bond formation during the oxygen evolution reaction using… read more here.
Keywords: spectroscopy; bond formation; direct identification; identification bond ... See more keywords