Lithium Diisopropylamide Catalyzed Allylic C-H Bond Alkylation with Styrenes.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b03108
Abstract: Allylic substitution reactions, a well-established approach for new bond construction, often need transition-metal catalysts and stoichiometric amounts of organometallic reagents, strong bases, or oxidants. Lithium diisopropylamide (LDA), a widely used and commercially available Brønsted base,… read more here.
Keywords: catalyzed allylic; bond; allylic bond; lithium diisopropylamide ... See more keywords
Unactivated Alkyl Halides in Transition-Metal-Catalyzed C–H Bond Alkylation
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c05580
Abstract: Alkylation represents an important organic transformation in molecular science to develop privileged alkylated arenes and heteroarenes. Especially, the direct C–H bond alkylation using unactivated ... read more here.
Keywords: alkyl halides; alkylation; unactivated alkyl; halides transition ... See more keywords