Hydrogen‐Bond‐Assisted Solution Discharge in Aprotic Li–O2 Batteries
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202110416
Abstract: Surface discharge mechanism induced cathode passivation is a critical challenge that blocks the full liberation of the ultrahigh theoretical energy density in aprotic Li–O2 batteries. Herein, a facile and universal concept of hydrogen‐bond‐assisted solvation is… read more here.
Keywords: bond assisted; hydrogen bond; discharge; solution discharge ... See more keywords
H-bond assisted coordination bond formation in the 1D chains based on azido and phenoxido bridged tetranuclear Cu(II) complexes with reduced Schiff base ligands
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2017.12.022
Abstract: Abstract Two new 1D chains [(CuL1R)2Cu2(N3)2(μ1,1,3-N3)2]n (1) and [{(CuL2R)2Cu2(N3)2(μ1,1,3-N3)2}·(CH3)2CO]n (2) based on rare μ1,1,3-N3 bridged tetranuclear Cu(II) complexes, have been synthesized using [CuL1R] and [CuL2R] as “metalloligands” [where H2L1R = N,N′-bis(2-hydroxybenzyl)-1,3-propanediamine and H2L2R = N,N′-bis(2-hydroxybenzyl)-1,2-ethylenediamine]. Both complexes have been… read more here.
Keywords: bond; tetranuclear complexes; bridged tetranuclear; tetranuclear ... See more keywords
Hydrogen-Bond-Assisted Symmetry Breaking in a Network of Chiral Metal-Organic Assemblies.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b12323
Abstract: Herein we elucidate the interplay of chiral, chelate, solvent, and hydrogen-bonding information in the self-assembly of a series of new three-dimensional metal-organic architectures. Enantiopure ligands, each containing H-bond donors and acceptors, form different structures, depending… read more here.
Keywords: hydrogen bond; metal organic; metal; symmetry ... See more keywords