Articles with "bond character" as a keyword



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USc2C2 and USc2NC Clusters with U-C Triple Bond Character Stabilized Inside Fullerene Cages.

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Published in 2023 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c10231

Abstract: The chemistry of f-block metal-carbon multiple bonds is underdeveloped compared to well-established carbene complexes of the d-block transition metals. Herein, we report two new actinide-rare earth mixed metal carbides and nitrogen carbide cluster fullerenes, USc2C2@D5h(6)-C80… read more here.

Keywords: usc2c2 usc2nc; bond character; chemistry; triple bond ... See more keywords