Recent advances in selective C-C bond coupling for ethanol upgrading over balanced Lewis acid-base catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Science China Materials"
DOI: 10.1007/s40843-019-9454-x
Abstract: Ethanol is a considerable platform molecule in biomass conversion, which could be acquired in quantity through acetone-butanol-ethanol (ABE) fermentation. People have been working on the upgrading of ethanol to value added chemicals for decades. In… read more here.
Keywords: lewis acid; bond; acid base; bond coupling ... See more keywords
Formation of Alkanes by Aerobic Carbon–Carbon Bond Coupling Reactions Catalyzed by a Phosphovanadomolybdic Acid
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DOI: 10.1021/acscatal.7b00461
Abstract: The valorization of alkanes is possible via carbon–carbon coupling reactions. A series of dialkyl cobalt complexes [(RCH2)2CoIII(bpy)2]ClO4 (R = H, Me, Et, and Ph) were reacted with the H5PV2Mo10O40 polyoxometalate as a catalyst, leading to… read more here.
Keywords: carbon; carbon bond; bond coupling; carbon carbon ... See more keywords
“One-Pot” CuCl2-Mediated Condensation/C–S Bond Coupling Reactions to Synthesize Dibenzothiazepines by Bi-Functional-Reagent N, N′-Dimethylethane-1,2-Diamine
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DOI: 10.3390/molecules27217392
Abstract: The efficient “One-pot” CuCl2-catalyzed C–S bond coupling reactions were developed for the synthesis of dibenzo[b,f][1,4]thiazepines and 11-methy-ldibenzo[b,f][1,4]thiazepines via 2-iodobenzaldehydes/2-iodoacetophenones with 2-aminobenzenethiols/2,2′-disulfanediyldianilines by using bifunctional-reagent N, N′-dimethylethane-1,2-diamine (DMEDA), which worked as ligand and reductant. The reactions… read more here.
Keywords: dimethylethane diamine; bond coupling; one pot; reagent dimethylethane ... See more keywords