Cleavage of an Aromatic C-C Bond in Ferrocene by Insertion of an Iridium Nitrido Nitrogen Atom.
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DOI: 10.1021/jacs.3c02781
Abstract: The intermolecular cleavage of C-C bonds is a rare event. Herein, we report on a late transition-metal terminal nitrido complex, which upon oxidation undergoes insertion of the nitrido nitrogen atom into the aromatic C-C bond… read more here.
Keywords: cleavage; bond ferrocene; aromatic bond; nitrido ... See more keywords