Catalytic C-H Bond Oxidation Using Dioxygen by Analogues of Heme Superoxide.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b03767
Abstract: Heme active sites are capable of oxidizing organic substrates by four electrons using molecular oxygen (heme dioxygenases), where a dioxygen (O2) adduct of heme (FeIII-O2•-) acts as the primary oxidant, in contrast to monooxygenases, where… read more here.
Keywords: oxidation; oxidation using; chemistry; bond oxidation ... See more keywords
Tailored Cl- Ligation on Supported Pt Catalysts for Selective Primary C-H Bond Oxidation.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c03257
Abstract: It is challenging to achieve high selectivity over Pt-metal-oxide catalysts widely used in many selective oxidation reactions because Pt is prone to over-oxidize substrates. Herein, our sound strategy for enhancing the selectivity is to saturate… read more here.
Keywords: tailored ligation; ligation supported; oxidation; primary bond ... See more keywords