Photoinduced Sulfur-Nitrogen Bond Rotation and Thermal Nitrogen Inversion in Heterocumulene OSNSO.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b12622
Abstract: An exotic ternary S, N, O heterocumulene OSNSO in syn-syn (A) and syn-anti (B) conformations has been generated in the gas phase through flash vacuum pyrolysis of CF3S(O)NSO at 700 K. Upon visible light irradiation… read more here.
Keywords: nitrogen; thermal nitrogen; bond rotation; nitrogen inversion ... See more keywords
Direct evidence for hula twist and single-bond rotation photoproducts
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DOI: 10.1038/s41467-018-04928-9
Abstract: Photoisomerization reactions are quintessential processes driving molecular machines and motors, govern smart materials, catalytic processes, and photopharmacology, and lie at the heart of vision, phototaxis, or vitamin production. Despite this plethora of applications fundamental photoisomerization… read more here.
Keywords: single bond; bond; hula twist; bond rotation ... See more keywords