Coordination-Induced Bond Weakening.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.2c00254
Abstract: Coordination-induced bond weakening is a phenomenon wherein ligand X-H bond homolysis occurs in concert with the energetically favorable oxidation of a coordinating metal complex. The coupling of these two processes enables thermodynamically favorable proton-coupled electron… read more here.
Keywords: coordination induced; bond weakening; induced bond; bond ... See more keywords
Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00298
Abstract: Highly reducing Sm(II) reductants and protic ligands were used as a platform to ascertain the relationship between low-valent metal-protic ligand affinity and degree of ligand X–H bond weakening with the goal of forming potent proton-coupled… read more here.
Keywords: bond weakening; ligand; smbr2 nmea; unusual reactivity ... See more keywords
Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00471
Abstract: The synthesis and characterization of a cationic molybdenum pyrrolidine complex are described that exhibits significant coordination-induced N–H bond weakening. The N–H bond dissociation free energ... read more here.
Keywords: pyrrolidine complex; induced bond; bond; molybdenum pyrrolidine ... See more keywords
Coordination-induced O-H bond weakening in Sm(ii)-water complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03352a
Abstract: The combination of Sm(ii)-based reductants with water provides reagent systems that promote a range of reductions and bond-forming reactions that are endergonic based on known redox potentials. Despite the utility of these reagent systems, little… read more here.
Keywords: induced bond; water; bond; bond weakening ... See more keywords