Diverse Bonding Activations in the Reactivity of a Pentaphenylborole toward Sodium Phosphaethynolate: Heterocycle Synthesis and Mechanistic Studies.
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DOI: 10.1021/acs.inorgchem.7b00128
Abstract: The reaction of the pentaphenylborole [(PhC)4BPh] (1) with sodium phosphaethynolate·1,4-dioxane (NaOCP(1,4-dioxane)1.7) afforded the novel sodium salt of phosphaboraheterocycle 2. It comprises anionic fused tetracyclic P/B-heterocycles that arise from multiple bond activation between the borole backbone… read more here.
Keywords: heterocycle; sodium; sodium phosphaethynolate; diverse bonding ... See more keywords