Fixation of CO2 into cyclic carbonates by halogen bonding catalysis.
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DOI: 10.1002/cssc.202002525
Abstract: Halogen bonding, parallel to hydrogen bonding, was introduced into the catalytic cycloaddition of carbon dioxide into epoxide (CCE) reactions. A series of halogen bond donor (XBD) catalysts of N -iodopyridinium halide featured with N-I bond… read more here.
Keywords: bonding catalysis; bond; cce reactions; halogen bonding ... See more keywords
Regiodivergent Nucleophilic Fluorination under Hydrogen Bonding Catalysis: A Computational and Experimental Study
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DOI: 10.1021/jacs.3c01303
Abstract: The controlled programming of regiochemical outcomes in nucleophilic fluorination reactions with alkali metal fluoride is a problem yet to be solved. Herein, two synergistic approaches exploiting hydrogen bonding catalysis are presented. First, we demonstrate that… read more here.
Keywords: hydrogen bonding; fluorination; hydrogen; bonding catalysis ... See more keywords
A Se···O bonding catalysis approach to the synthesis of calix[4]pyrroles
Sign Up to like & getrecommendations! Published in 2022 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.18.36
Abstract: Described herein is a chalcogen bonding catalysis approach to the synthesis of calix[4]pyrrole derivatives. The Se···O bonding interactions between selenide catalysts and ketones gave rise to the catalytic activity in the condensation reactions between pyrrole… read more here.
Keywords: bonding catalysis; calix; approach synthesis; catalysis approach ... See more keywords