Halogen-Bonding-Mediated Radical Reactions: The Unexpected Behavior of Piperazine-Based Dithiooxamide Ligands in the Presence of Diiodine
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DOI: 10.1021/acs.inorgchem.2c02340
Abstract: N,N′-Dialkylpiperazine-2,3-dithiones (R2pipdt) were recognized as a class of hexa-atomic cyclic dithiooxamide ligands with peculiar charge-transfer donor properties toward soft electron-acceptors such as noble metal cations and diiodine. The latter interaction is nowadays better described as… read more here.
Keywords: halogen; mediated radical; halogen bonding; dithiooxamide ligands ... See more keywords
Hydrogen Bonding-Mediated Enhancement of Bioinspired Electrochemical Nitrogen Reduction on Cu2–xS Catalysts
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DOI: 10.1021/acscatal.0c01730
Abstract: The electrochemical nitrogen reduction reaction (NRR) has been regarded as a promising alternative to the conventional Haber-Bosh process for NH3 synthesis. Inspired by the Fe-Mo-S cofactor in the ... read more here.
Keywords: bonding mediated; hydrogen bonding; nitrogen reduction; electrochemical nitrogen ... See more keywords