Hydrogen bonding promotes diversity in nitrite coordination modes at a single iron(II) center
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DOI: 10.1080/00958972.2020.1821373
Abstract: Abstract A low-valent [FeN5(OTf)2] complex and its bisnitrite adduct, [FeN5(NO2)2], have been synthesized in the interest of extending the reactivity of Fe complexes featuring redox-active ligands with secondary coordination sphere hydrogen-bond donors to nitrite reduction.… read more here.
Keywords: coordination; bonding promotes; coordination modes; nitrite ligands ... See more keywords