Nitrile Infrared Intensities Characterize Electric Fields and Hydrogen Bonding in Protic, Aprotic, and Protein Environments.
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DOI: 10.1021/jacs.2c00675
Abstract: Nitriles are widely used vibrational probes; however, the interpretation of their IR frequencies is complicated by hydrogen bonding (H-bonding) in protic environments. We report a new vibrational Stark effect (VSE) that correlates the electric field… read more here.
Keywords: nitrile infrared; bonding protic; hydrogen bonding; infrared intensities ... See more keywords