Copper(I) activation of C-X bonds: bimolecular vs. unimolecular reaction mechanism.
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DOI: 10.1039/d1cc07027d
Abstract: Experimental kinetic studies and DFT calculations show that the oxidative addition of aryl halides (Ar-X) to complexes [Cu(NHC)R] follow different paths depending on the nature of X. For X = Br a concerted addition leads… read more here.
Keywords: copper activation; reaction; reaction mechanism; bonds bimolecular ... See more keywords