Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2019 at "Advanced materials"
DOI: 10.1002/adma.201806163
Abstract: Transformation of CO2 based on metal-organic framework (MOF) catalysts is becoming a hot research topic, not only because it will help to reduce greenhouse gas emission, but also because it will allow for the production… read more here.
Keywords: formation bonds; bonds co2; co2 chemical; metal organic ... See more keywords
Photochemical Carboxylation of Activated C(sp3 )-H Bonds with CO2.
Sign Up to like & getrecommendations! Published in 2017 at "ChemSusChem"
DOI: 10.1002/cssc.201700205
Abstract: From ugly duckling to beautiful C1: Although CO2 may represent an ideal C1 source, it is challenging to use it as a raw material and direct carboxylation with CO2 has mainly been confined to highly… read more here.
Keywords: bonds co2; photochemical carboxylation; sp3 bonds; activated sp3 ... See more keywords
Carbon-carbon bonds with CO2: Insights from computational studies
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.02.020
Abstract: Abstract In this mini-review, we provide an overview of recent computational studies on homogeneous transition metal-catalyzed carbon-carbon bond formation with CO2. We cover substitution and addition reactions involving different metals (mainly Ni, Rh, Cu) and… read more here.
Keywords: carbon bonds; bonds co2; carbon; bond formation ... See more keywords
Catalytic Lactonization of Unactivated Aryl C-H Bonds with CO2: Experimental and Computational Investigation.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b01363
Abstract: The first catalytic lactonization of unactivated aryl C-H bonds with CO2 to afford important phthalides is reported. Notably, this method features high selectivity, excellent functional group tolerance, smooth scalability, and facile product diversification. DFT calculations… read more here.
Keywords: bonds co2; aryl bonds; lactonization unactivated; catalytic lactonization ... See more keywords
Pd(II)-catalyzed carboxylation of aromatic C─H bonds with CO2
Sign Up to like & getrecommendations! Published in 2023 at "Science Advances"
DOI: 10.1126/sciadv.adf2966
Abstract: The carboxylation of nonactivated C─H bonds provides an attractive yet hitherto largely elusive chemical process to synthesize carboxylic acids by incorporation of CO2 into the chemical value chain. Here, we report on the realization of… read more here.
Keywords: bonds co2; carboxylation; chemistry; aromatic bonds ... See more keywords