Insertion of Isonitriles into the M-C Bonds of Group 4 Dialkyl Complexes.
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DOI: 10.1021/jacs.8b05377
Abstract: The 2,3-dimethylbutadiene complexes of Group 4 metals with constrained geometry (cg) ligands have been prepared and found to adopt a supine orientation with σ2,π bonding. Treatment of cgTi(2,3-dimethylbutadiene) (1-Ti) with tBuNC leads to the formation… read more here.
Keywords: isonitriles bonds; insertion; group; insertion isonitriles ... See more keywords