Photofluorination of Aliphatic C-H Bonds Promoted by the Phthalimide Group.
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DOI: 10.1021/acs.orglett.8b00133
Abstract: Aliphatic C-H fluorination of phthalimide derivatives with Selectfluor was investigated under photoirradiation conditions. The reaction did not require any additive or catalyst and afforded C-H fluorinated products in moderate to good yields. It is likely… read more here.
Keywords: aliphatic bonds; bonds promoted; promoted phthalimide; photofluorination aliphatic ... See more keywords
Photocatalytic Construction of S-S and C-S Bonds Promoted by Acridinium Salt: An Unexpected Pathway To Synthesize 1,2,4-Dithiazoles.
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DOI: 10.1021/acs.orglett.8b01970
Abstract: An unexpected cyclization of thioamides with p-quinone methides promoted by acridinium salt under the irradiation of visible light furnished 1,2,4-dithiazoles in moderate to good yields. In addition, the reaction of the obtained 1,2,4-dithiazoles with isocyanides… read more here.
Keywords: promoted acridinium; photocatalytic construction; bonds promoted; construction bonds ... See more keywords