Allylation of C(sp 3 )─H Bonds Using a MW/Persulfate Protocol
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DOI: 10.1002/hlca.202500191
Abstract: The C(sp 3 )─H allylation reaction using allyl phenyl sulfone was affected by persulfate anion (PS) under microwave (MW) irradiation. The MW/PS protocol has been found to be applicable to a wide variety of C(sp… read more here.
Keywords: protocol; persulfate protocol; allylation; allylation bonds ... See more keywords
Photocatalytic Methylation of Nonactivated sp3 and sp2 C–H Bonds Using Methanol on GaN
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DOI: 10.1021/acscatal.0c00881
Abstract: Although the development of C-H functionalization methods has enlightened many new reactivities in chemistry, the direct functionalization of unactivated C-H bonds, which are particularly common in... read more here.
Keywords: methylation nonactivated; nonactivated sp3; bonds using; photocatalytic methylation ... See more keywords
Cr-catalyzed borylation of C(aryl)-F bonds using a terpyridine ligand.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc01330a
Abstract: The defluoroborylation of fluoroarenes by chromium-catalyzed cleavage of unactivated C-F bonds is described. The reaction uses HBpin as the boron source, low-cost and commercially available chromium salt as the precatalyst, and terpyridine as a crucial… read more here.
Keywords: aryl bonds; ligand; borylation aryl; catalyzed borylation ... See more keywords