Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides.
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DOI: 10.1021/acs.inorgchem.1c02124
Abstract: Reactions of 9-carbene-9-borafluorene monoanion (1) with elemental selenium and selenium-containing reagents are reported. When compound 1 is reacted with grey selenium in THF, various boryl-substituted selenides and diselenides are produced (2-6), including molecules resulting from… read more here.
Keywords: boryl substituted; borafluorene monoanion; reactions carbene; carbene borafluorene ... See more keywords
Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone.
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DOI: 10.1021/jacs.2c06845
Abstract: The first structurally characterized example of a trioxaborinanone (2) is produced by the reaction of a 9-carbene-9-borafluorene monoanion and carbon dioxide. When compound 2 is heated or irradiated with UV light, carbon monoxide (CO) is… read more here.
Keywords: carbon; carbene borafluorene; monoanion carbon; borafluorene monoanion ... See more keywords