In situ generation of radical initiators using amine-borane complexes for carbohalogenation of alkenes.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06390a
Abstract: Atom transfer radical addition of alkyl halides to alkenes was developed using a low amount of a stable initiator, amine borane complexes. Thanks to a slow hydroboration step, the overall carbohalogenation process leads to good… read more here.
Keywords: borane complexes; carbohalogenation; generation radical; situ generation ... See more keywords
N -Alkyl-1,2,4-triazole–Borane Complexes as High-Density Hypergolic Materials
Sign Up to like & getrecommendations! Published in 2024 at "Synlett"
DOI: 10.1055/a-2310-0707
Abstract: Hydrazine and its derivatives have served as a conventional bipropellant fuel for several decades. However, their extremely acute toxicity and carcinogenicity, high volatility, and environmental impact have attracted significant attention. In order to synthesize green… read more here.
Keywords: high density; alkyl triazole; density; hypergolic materials ... See more keywords