Controlling the fluoridophilicity of sulfonium boranes via chelation, Coulombic and hydrophobic effects
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.01.035
Abstract: Abstract We describe the synthesis and properties of a series of sulfonium boranes featuring a dimesitylboryl unit and a dimethylsulfonium or methylphenyl sulfonium moiety connected by an ortho- or para-phenylene linker. Acid-base and fluoride anion… read more here.
Keywords: boranes via; controlling fluoridophilicity; c6h4 smeph; sulfonium ... See more keywords
Selective Multifunctionalization of N-Heterocyclic Carbene Boranes via the Intermediacy of Boron-Centered Radical
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc01132a
Abstract: Selective difunctionalization of N-heterocyclic carbene (NHC) boranes with alkenes has been achieved via the decatungstate and thiol synergistic catalysis. The catalytic system also allows the stepwise trifunctionalization, leading to complex... read more here.
Keywords: carbene boranes; selective multifunctionalization; heterocyclic carbene; boranes via ... See more keywords