Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc00245b
Abstract: A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C-B bond occurs via single electron reduction by a Cu(i) photocatalyst activated by… read more here.
Keywords: single electron; electron reduction; generation; via single ... See more keywords
Ruthenium tris(σ-B-H) borate complexes: synthesis, structure, and reactivity.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03092f
Abstract: The coordination of the B-H bond to a transition metal is fundamentally intriguing due to its connection with the transition metal-mediated B-H bond activation mechanism and catalysis. Most of the reported examples are σ-borane/borate complexes… read more here.
Keywords: borate; ruthenium tris; transition metal; borate complexes ... See more keywords