Borinic Acid-Catalyzed, Regioselective Ring Opening of 3,4-Epoxy Alcohols.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b02295
Abstract: Diarylborinic acids (Ar2BOH) catalyze the C3-selective ring opening of 3,4-epoxy alcohols with aniline, dialkylamine and arenethiol nucleophiles. The regiochemical outcome is consistent with a catalytic tethering mechanism in which the borinic acid interacts with both… read more here.
Keywords: ring opening; borinic acid; epoxy alcohols; acid catalyzed ... See more keywords
Promoting water dissociation performance by borinic acid for the strong-acid/base-free hydrogen evolution reaction.
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DOI: 10.1039/c9cc04569d
Abstract: A new type of organic proton donor for the strong-acid/base-free hydrogen evolution reaction is reported, by taking advantage of the electron deficiency of the boron center of borinic acid and the strong affinity and hydrolysis… read more here.
Keywords: borinic acid; hydrogen; hydrogen evolution; reaction ... See more keywords
Copper- and Borinic Acid-catalyzed Propargylic Etherification of Propargylic Carbonates with Benzyl Alcohols
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DOI: 10.1246/cl.180123
Abstract: Propargylic substitution reactions have offered useful synthetic methods because further transformations based on the alkyne moiety in the propargylic substituted products was readily achieved to construct more complex organic compounds. A large number of works… read more here.
Keywords: borinic acid; copper borinic; acid catalyzed; catalyzed propargylic ... See more keywords